ResearchPad - molecular-switches https://www.researchpad.co Default RSS Feed en-us © 2020 Newgen KnowledgeWorks <![CDATA[Photoswitchable Norbornadiene–Quadricyclane Interconversion Mediated by Covalently Linked C<sub>60</sub> ]]> https://www.researchpad.co/article/elastic_article_6851 Switching! The synthesis of several norbornadiene (NBD)–fullerene adducts is herein reported. Within these new hybrid systems, the photochemical isomerization of NBD is combined with the electron affinity of C60. This enables the selective light‐induced isomerization of the NBD derivative to its corresponding quadricyclane (QC) counterpart and the back conversion of the latter mediated by the photochemically excited fullerene core.

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