ResearchPad - nitrogen-fixation-|-very-important-paper Default RSS Feed en-us © 2020 Newgen KnowledgeWorks <![CDATA[(Electro‚Äź)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex]]> N2 splitting into terminal nitrides by chemical and electrochemical reduction of [ReCl2{N(CHCHPtBu2)2}] is presented. Comparison of electrochemical data with that of the previously reported, related pincer complex [ReCl2{N(CH2CH2PtBu2)2}] allowed for identifying key parameters that control the efficiency of the reaction sequence, which defines reductive N2 splitting.John Wiley & Sons, Ltd.